Why we are on the topic of innovation from Israel (nano-Satellites) anther team has found away to half split water with 100% efficiency
Splitting water is a two-step process, and in a new study, researchers have performed one of these steps (reduction) with 100% efficiency. The results shatter the previous record of 60% for hydrogen production with visible light, and emphasize that future research should focus on the other step (oxidation) in order to realize practical overall water splitting. The main application of splitting water into its components of oxygen and hydrogen is that the hydrogen can then be used to deliver energy to fuel cells for powering vehicles and electronic devices.
The 100% efficiency refers to the photon-to-hydrogen conversion efficiency, and it means that virtually all of the photons that reach the photocatalyst generate an electron, and every two electrons produce one H2 molecule. At 100% yield, the half-reaction produces about 100 H2 molecules per second (or one every 10 milliseconds) on each nanorod, and a typical sample contains about 600 trillion nanorods.
One of the keys to achieving the perfect efficiency was identifying the bottleneck of the process, which was the need to quickly separate the electrons and holes (the vacant places in the semiconductor left after the electrons leave), and remove the holes from the photocatalyst. To improve the charge separation, the researchers redesigned the nanorods to have just one platinum catalyst instead of two. The researchers found that the efficiency increased from 58.5% with two platinum catalysts to 100% with only one.
The researchers, Philip Kalisman, Yifat Nakibli, and Lilac Amirav at the Technion-Israel Institute of Technology in Haifa, Israel, have published a paper on the perfect efficiency for the water reduction half-reaction in a recent issue of Nano Letters.
“I strongly believe that the search for clean and renewable energy sources is crucial,” Amirav told Phys.org. “With the looming energy crisis on one hand, and environmental aspects, mainly global warming, on the other, I think this is our duty to try and amend the problem for the next generation.
“Our work shows that it is possible to obtain a perfect 100% photon-to-hydrogen production efficiency, under visible light illumination, for the photocatalytic water splitting reduction half-reaction. These results shatter the previous benchmarks for all systems, and leave little to no room for improvement for this particular half-reaction. With a stable system and a turnover frequency of 360,000 moles of hydrogen per hour per mole of catalyst, the potential here is real.”
Going forward, the researchers plan to further improve the system. The current demonstration requires a very high pH, but such strong basic conditions are not always ideal in practice. Another concern is that the cadmium sulfide (CdS) used in the nanorod becomes corroded under prolonged light exposure in pure water. The researchers are already addressing these challenges with the goal to realize practical solar-to-fuel technology in the future.
“We hope to implement our design rules, experience and accumulated insights for the construction of a system capable of overall water splitting and genuine solar-to-fuel energy conversion,” Amirav said. “The photocatalytic hydrogen generation presented here is not yet genuine solar-to-fuel energy conversion, as hole scavengers are still required. CdS is unfortunately not suitable for overall water splitting since prolonged irradiation of its suspensions leads to photocorrosion. We have recently demonstrated some breakthrough on this direction as well. The addition of a second co-catalyst, such as IrO2 or Ru, which can scavenge the holes from the semiconductor and mediate their transfer to water, affords CdS-based structures the desired photochemical stability. I believe this is an important milestone.”
Perfect Photon-to-Hydrogen Conversion Efficiency
Full Story: http://m.phys.org/news/2016-02-scientists-efficiency-water-splitting-half-reaction.html