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    Garden grass could become a source of cheap and clean renewable energy, scientists have claimed.

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    A team of UK researchers, including experts from Cardiff University’s Cardiff Catalysis Institute, have shown that significant amounts of hydrogen can be unlocked from fescue grass with the help of sunlight and a cheap catalyst.

    It is the first time that this method has been demonstrated and could potentially lead to a sustainable way of producing hydrogen, which has enormous potential in the renewable energy industry due to its high energy content and the fact that it does not release toxic or greenhouse gases when it is burnt.

    Co-author of the study Professor Michael Bowker, from the Cardiff Catalysis Institute, said: “This really is a green source of energy.”Hydrogen is seen as an important future energy carrier as the world moves from fossil fuels to renewable feedstocks, and our research has shown that even garden grass could be a good way of getting hold of it.”

    The team, which also includes researchers from Queen’s University Belfast, have published their findings in the Royal Society journal Proceedings A.

    Hydrogen is contained in enormous quantities all over in the world in water, hydrocarbons and other organic matter. Up until now, the challenge for researchers has been devising ways of unlocking hydrogen from these sources in a cheap, efficient and sustainable way.

    A promising source of hydrogen is the organic compound cellulose, which is a key component of plants and the most abundant biopolymer on Earth.

    In their study, the team investigated the possibility of converting cellulose into hydrogen using sunlight and a simple catalyst — a substance which speeds up a chemical reaction without getting used up.

    This process is called photoreforming or photocatalysis and involves the sunlight activating the catalyst which then gets to work on converting cellulose and water into hydrogen. The researchers studied the effectiveness of three metal-based catalysts — Palladium, Gold and Nickel.

    Nickel was of particular interest to the researchers, from a practical point of view, as it is a much more earth-abundant metal than the precious metals, and is more economical.In the first round of experiments, the researchers combined the three catalysts with cellulose in a round bottom flask and subjected the mixture to light from a desk lamp. At 30 minutes intervals the researchers collected gas samples from the mixture and analysed it to see how much hydrogen was being produced.

    F8.medium

    Influence of the co-catalyst on the hydrogen evolution for cellulose photoreforming (a) and for glucose photoreforming (b). Reaction conditions: 200 mg cellulose (a) and 25 mg l−1 glucose (b), 200 ml H2O, 150 mg catalyst, temperature = 60°C. The inset figure shows the H2 production rate for each catalyst.

    To test the practical applications of this reaction, the researchers repeated the experiment with fescue grass, which was obtained from a domestic garden. Professor Michael Bowker continued: “Up until recently, the production of hydrogen from cellulose by means of photocatalysis has not been extensively studied.”Our results show that significant amounts of hydrogen can be produced using this method with the help of a bit of sunlight and a cheap catalyst.

    “Furthermore, we’ve demonstrated the effectiveness of the process using real grass taken from a garden. To the best of our knowledge, this is the first time that this kind of raw biomass has been used to produce hydrogen in this way. This is significant as it avoids the need to separate and purify cellulose from a sample, which can be both arduous and costly.”

    Paper

    http://rspa.royalsocietypublishing.org/content/472/2191/20160054

    Abstract

    Here, we report a method for sustainable hydrogen production using sunlight and biomass. It is shown that cellulose can be photoreformed to produce hydrogen, even in solid form, by use of metal-loaded titania photocatalysts. The experiments performed verified that the process is enabled by initial hydrolysis via glucose, which itself is shown to be efficiently converted to produce hydrogen by photocatalysis. Importantly, it is shown that not only precious metals such as Pt, Pd and Au can be used as the metal component, but also much more economic and less environmentally damaging Ni is effective. Even more importantly, we show for the first time, to the best our knowledge, that fescue grass as raw biomass can be effective for hydrogen production without significant pre-treatment. This provides additional benefits for the efficiency of biomass hydrogen production, because fewer processing steps for the raw material are required than in the production of purer forms of cellulose, for example.

     Conclusion

    In this study, we have clearly demonstrated that hydrogen can be produced by photoreforming of cellulose/water mixtures over TiO2 catalysts loaded with metal nanoparticles. Importantly, catalysts based on non-noble metals as well as platinum group metal materials are very effective. For example, the use of much less expensive Ni has been shown to be highly active for hydrogen production, particularly if a pre-reduction step is performed. It is proposed, based on the study of the rate law for cellulose and glucose, that the first step in the photoreforming of cellulose is the (photo)hydrolysis of cellulose into glucose, with the latter then undergoing reforming to hydrogen and CO2. To further illustrate the practicality of the process, fescue grass has been shown to be a suitable raw biomass sacrificial donor, producing a significant amount of H2 by photoreforming. This process shows high potential for efficient hydrogen economy, because it allows the production of hydrogen directly from the main component of biomass (cellulose), avoiding any intermediate transformation steps (fermentation, etc.) over low loading metal/TiO2 catalysts.

    Reference

    http://rspa.royalsocietypublishing.org/content/472/2191/20160054

    Michael Bishop
    Communications & Marketing
    Cardiff University
    Tel: 02920-874499 / 07713-325300
    Email: BishopM1@cardiff.ac.uk

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